Intraband plasmon

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lz dong
Posts: 11
Joined: Mon Jun 12, 2023 7:26 am

Intraband plasmon

Post by lz dong » Sun Oct 20, 2024 5:44 pm

Dear all,
I would like to know, does the electron energy loss spectrum calculated by BSE, contain both intraband and interband plasmon transitions? Or do we need to do additional RPA calculations to obtain the intraband and interband plasmon energy?


Best,
lz Dong
PhD student
Beijing Institute of Technology,China

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Daniele Varsano
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Re: Intraband plasmon

Post by Daniele Varsano » Mon Oct 21, 2024 7:58 am

Dear lz Dong,
I assume you are dealing with a metallic system.
Intraband transitions are included (hence also the plasmon is reproduced.). Interband are automatically included at finite momentum, while they are not in the long wavelength limit (q-->0). In this case, you can use a Drude (with empirical parameters) model to take it into account.

Best,
Daniele
Dr. Daniele Varsano
S3-CNR Institute of Nanoscience and MaX Center, Italy
MaX - Materials design at the Exascale
http://www.nano.cnr.it
http://www.max-centre.eu/

lz dong
Posts: 11
Joined: Mon Jun 12, 2023 7:26 am

Re: Intraband plasmon

Post by lz dong » Wed Oct 23, 2024 3:20 pm

Daniele Varsano wrote: Mon Oct 21, 2024 7:58 am Dear lz Dong,
I assume you are dealing with a metallic system.
Intraband transitions are included (hence also the plasmon is reproduced.). Interband are automatically included at finite momentum, while they are not in the long wavelength limit (q-->0). In this case, you can use a Drude (with empirical parameters) model to take it into account.

Best,
Daniele

Dear Daniele,
Thank you very much for your reply. For a semiconductor with a small energy gap, both intraband and interband contributions should also be included at finite momentum, right?
lz Dong
PhD student
Beijing Institute of Technology,China

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Daniele Varsano
Posts: 4198
Joined: Tue Mar 17, 2009 2:23 pm
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Re: Intraband plasmon

Post by Daniele Varsano » Sat Oct 26, 2024 9:07 am

Dear lz Dong,

I'm not sure that I've correctly understood your question,
in the presence of a gap (even if it is small), at zero temperature intraband transitions are not allowed as each band is either fully occupied or empty.

Best,
Daniele
Dr. Daniele Varsano
S3-CNR Institute of Nanoscience and MaX Center, Italy
MaX - Materials design at the Exascale
http://www.nano.cnr.it
http://www.max-centre.eu/

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